The counterfeit pills are green in colour and have a crown logo - there are also warnings of a white pill with a Mitsubishi logo.
A teenager has died after taking "dangerous" fake ecstasy tablets - the seventh reported death linked to the pills.
In the latest case, an 18-year-old woman died in Alexandria, West Dunbartonshire, on Tuesday morning.
Three male friends aged 18, 21 and 25 were admitted to the Royal Alexandra Hospital. Doctors are still treating the 25-year-old.
In recent weeks there has been a rise in the number of people who have died after taking a tablet that they thought was ecstasy. The majority of these were people in their early 20s.
Police in the west of Scotland have identified the pills as green in colour and stamped with a crown logo and say some have been found to contain a dangerous stimulant called Methoxyamphetamine, also known as PMA.
They are also warning of a white pill with the Mitsubishi logo imprinted on it, found to contain the chemicals 5IT or AMT, and a yellow tablet with a star logo.
Officers in the north of Scotland recovered a large quantity of fake ecstasy tablets at a house in Aberdeen on Tuesday. These tablets are also green but with the Heineken logo.
"The tablets were described as green with a Rolex crown logo stamped on them.
"Public warnings have been issued recently in relation to the dangers of taking ecstasy, or indeed tablets being passed off as ecstasy. They are illegal and could contain a cocktail of toxic ingredients.
"We have yet to establish if this particular pill is to blame for the death of this young woman, but the fact that she and her friends took pills described as green and with a Rolex stamp on it causes us real concern.
"The exact contents of the pills are unknown but they could contain dangerous chemicals."
People taking the fake pills can experience symptoms including high temperature, aggression and muscle pains as well as hallucinations and excitability, medics said.
Richard Stevenson, a doctor in emergency medicine at Glasgow Royal Infirmary, said: "These symptoms are treatable if help is sought early. I would urge anyone who begins to feel unwell or feels a more intense high than usual after taking any drug which they think is ecstasy or not to seek immediate medical help."
Police are keen to get the warning across ahead of this weekend's T in the Park music festival in Balado, Perth and Kinross.
Drugs "amnesty bins" will be available at the entrance to the campsites where illegal substances can be disposed of without risk of prosecution, police said.
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